Catalytic Methane Monofunctionalization by an Electrogenerated High-Valent Pd Intermediate
نویسندگان
چکیده
منابع مشابه
Catalytic Methane Monofunctionalization by an Electrogenerated High-Valent Pd Intermediate
Electrophilic high-valent metal ions are potent intermediates for the catalytic functionalization of methane, but in many cases, their high redox potentials make these intermediates difficult or impossible to access using mild stoichiometric oxidants derived from O2. Herein, we establish electrochemical oxidation as a versatile new strategy for accessing high-valent methane monofunctionalizatio...
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ژورنال
عنوان ژورنال: ACS Central Science
سال: 2017
ISSN: 2374-7943,2374-7951
DOI: 10.1021/acscentsci.7b00342